Formation of multistage garnet grains by fragmentation and overgrowth constrained by microchemical and microstructural mapping

Paola Manzotti, Daniele Regis, Duane C. Petts, Riccardo Graziani, Matthew Polivchuk

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Abstract
Garnet is an exceptionally useful mineral for reconstructing the evolution of metamorphic rocks that have experienced multiple tectonic or thermal events. Understanding how garnet crystallizes and its mechanical behaviour is important for establishing a petrological and temporal record of metamorphism and deformation and for recognizing multiple geologic stages within the growth history of an individual crystal. Here, we integrate fine-scale microstructural (electron backscatter diffraction [EBSD]) and microchemical (Laser Ablation Inductively Coupled Plasma Mass Spectrometry [LA-ICP-MS] mapping) data obtained on a polycyclic garnet-bearing micaschist from the Alpine belt. Results suggest that fragmentation of pre-Alpine garnet porphyroblasts occurred during the late pre-Alpine exhumation and/or the onset of the Alpine burial, such that the older pre-Alpine garnet fragments were transported/redistributed during Alpine deformation and acted as nucleation sites for Alpine garnet growth. These processes produced a bimodal garnet size distribution (millimetre- and micrometre-sized grains). Thermodynamic modelling indicates that Alpine garnet grew during the final stage of burial (from 1.9 GPa 480°C to 2.0 GPa 520°C) and early exhumation (down to 1.6 GPa 540°C) forming continuous idioblastic rims on and sealing fractures in pre-Alpine garnet grains. We propose that fragmentation–overgrowth processes in polycyclic rocks, coupled with ductile deformation, may produce a bimodal garnet size distribution in response to fragmentation and re-distribution of pre-existing grains; these clasts can act as new nucleation sites during a subsequent orogenic cycle.

(a) Garnet–chloritoid micaschist from the Gran Paradiso Massif (Valnontey valley) characterized by a microfolded early S1 foliation defined by quartz domains and the shape preferred orientation of white mica and chloritoid. The white arrows indicate the location of millimetre-sized garnet grains (i.e., macro-grains). (b) Millimetre-sized dark red macro-grains (white arrows) display irregular shapes and are wrapped by the matrix foliation. N, north; S, south. [Color figure can be viewed at wileyonlinelibrary.com]