Stockholm university

Research group PGA group

Stereoselective synthesis is a crucial process in organic chemistry and is extremely important in the field of pharmaceuticals, as the different enantiomers or diastereomers of a molecule often have different biological activity.

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For the past two decades, our group has gained experience in the field of metal-catalyzed asymmetric hydrogenation. During this period, novel metal catalysts were developed and applied in the hydrogenation of various classes of substrates, including challenging aliphatic- and tetrasubstituted olefins. Recent developed protocols include advances in regioselective hydrogenation of dienes, synthesis of chiral fluorine motifs and dynamic kinetic resolution of allylic alcohols.

Current interests lay in:

- Methodology development using transition metal-catalyzed asymmetric hydrogenation, such as;

  • Enantioconvergent hydrogenation where both E- and Z-olefins lead to the same absolute configuration of the product.
  • (Dynamic) kinetic resolution of various classes of functionalized olefins.
  • Synthesis of chiral fluorine scaffolds.

- Application of developed methodology in total synthesis of natural products and pharmaceuticals.

Group members

Group managers

Pher Andersson

Professor

Department of Organic Chemistry

Members

Rajendra Kumar Mallick

Postdok

Department of Organic Chemistry